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Combined Experimental and Computational Investigations of Rhodium- and Ruthenium-Catalyzed CH Functionalization of Pyrazoles with Alkynes
Detailed experimental and computational studies are reported on the mechanism of the coupling of alkynes with 3-arylpyrazoles at [Rh(MeCN)3Cp*][PF6]2 and [RuCl2(p-cymene)]2 catalysts. Density functional theory (DFT) calculations indicate a mechanism ...Journal of Organic Chemistry, 1 week ago
Ruthenium-Nitrosyl Complexes with Glycine, l-Alanine, l-Valine, l-Proline, d-Proline, l-Serine, l-Threonine, and l-Tyrosine: Synthesis, X-ray Diffraction Structures, Spectroscopic and Electrochemical Properties, and Antiproliferative Activity
The reactions of [Ru(NO)Cl5]2 with glycine (Gly), l-alanine (l-Ala), l-valine (l-Val), l-proline (l-Pro), d-proline (d-Pro), l-serine (l-Ser), l-threonine (l-Thr), and l-tyrosine (l-Tyr) in n-butanol or n-propanol afforded eight new complexes (18) ...Inorganic Chemistry, 2 weeks ago
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology , 2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan Organometallics , Article ASAP DOI: 10.1021/om5000248 Publication Date (Web): ...Organometallics, 2 weeks ago
The regio- and enantioselective allylic amination of racemic monosubstituted allylic esters, such as 1-arylallyl acetates, with cyclic secondary amines has been accomplished. The RuCl3/(S,S)-ip-pybox catalyst system has effectively catalyzed the ...Organic Letters, 3 weeks ago
Ruthenium Complex Catalysts Supported by a Bis(trifluoromethyl)pyrazolylPyridyl-Based NNN Ligand for Transfer Hydrogenation of Ketones
Ru(III) and Ru(II) complexes bearing a tridentate 2-(3′,5′-dimethylpyrazol-1′-yl)-6-(3″,5″-bis(trifluoromethyl)pyrazol-1″-yl)pyridine or 2-(benzimidazol-2′-yl)-6-(3″,5″-bis(trifluoromethyl)pyrazol-1″-yl)pyridine ligand were ...Organometallics, 3 weeks ago POPPincer Ruthenium Complexes: d6 Counterparts of Osmium d4 Species Inorganic Chemistry, 1 month ago
Spectroscopic and physico-chemical characterization of Ir(I) and Ru(III) complexes of 32-membered unsymmetrical dinucleating macrocyclic ligand
368 Downloads 200 Citations Purchase on Springer.com $39.95 / €34.95 / £29.95* Rent the article at a discount Rent now * Final gross prices may vary according to local VAT. Get Access Abstract Reactions of the ...Springer Link Journal, 1 month ago
Chiral (η6-p-Cymene)ruthenium(II) Complexes Containing Monodentate Acylthiourea Ligands for Efficient Asymmetric Transfer Hydrogenation of Ketones
The new chiral ligands (R)-/(S)-N-((1-phenylethyl)carbamothioyl)benzamide (L1/L2), (R)-/(S)-N-((1-phenylethyl)carbamothioyl)thiophene-2-carboxamide (L3/L4), and (R)-/(S)-N-((1-phenylethyl)carbamothioyl)furan-2-carboxamide (L5/L6) were synthesized, ...Organometallics, 1 month ago
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