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About 10 results for "rucl"

Flower-like RuCu Nanodendrites as Catalysts for Hydrogenation ...

Flower-like ruthenium-copper (RuCu) nanodendrites were readily synthesized by RuCl 3 ·xH 2 O and CuCl with oleylamine as reducing agent, stabilizer and solvent. The nanodendrites contained various small particles and demonstrated efficiently ... RSC, 2 weeks ago

Catalytic activity assessment of [RuCl 2 ( p -cymene) (PTA)] in the synthesis of enol esters

Rent the article at a discount Rent now * Final gross prices may vary according to local VAT. Get Access Abstract The addition of carboxylic acids onto 1-hexyne was catalyzed by [RuCl 2 ( p -cymene) (PTA)] complex to give enol esters.
 Springer Link Journal1 month ago

Unprecedented flexibility of the 1,1[prime or minute]-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B-H[right harpoon up]Ru interactions

Doubly-deprotonated 1,1′-bis( o -carborane) reacts with [RuCl 2 ( p -cymene)] 2 to afford [Ru(κ 3 -2,2′,3′-{1-(1′-1′,2′- closo -C 2 B 10 H 10 )-1,2- closo -C 2 B 10 H 10 })( p -cymene)] ( 1 ) in which 1,1′-bis( o -carborane) acts as ...
 RSC2 months ago

Synthesis of Aromatic Ruthenabenzothiophenes via C-H Activation of Thiophenes

Reaction of RuCl 2 (PPh 3 ) 3 with thiophenyl propynol and PPh 3 produces the ruthenacyclic complex, which can convert to the bisruthenabenzothiophene in the presence of acid via the intramolecular C-H activation of thiophene. The ...
 RSC2 months ago

Structural analysis of monometallic ruthenium-arene complexes using ion mobility mass spectrometry, collision-induced dissociation, and density functional theory

Ion mobility mass spectrometry (IM-MS) and collision-induced dissociation (CID) techniques were used to investigate the influence of the phosphine ligand on the physicochemical properties of [RuCl 2 ( p -cymene)(PCy 3 )] ( 1 ), [RuCl 2 ( p ...
 RSC1 week ago

Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones

Five ruthenium (II) complexes were synthesized, including (HO-C5H3N-CH2-C5H3N-C5H4N)Ru(PPh3)Cl2 (3), [(HO-C5H3N-CH2-C5H3N-C5H4N)Ru(PPh3)2Cl][PF6] (4) and [(HO-C5H3N-CH2-C5H3N-C5H4N)Ru(PPh3)2OH][PF6] (5) bearing an unsymmetrical pincer NNN ligand ...
 RSC1 week ago

Ionic Liquid Mediated Deposition of Ruthenium Mirrors on Glass under Multiphase Conditions

Shiny metallic mirrors of Ru nanoparticles (2-4 nm) have been deposited on borosilicate glass in the presence of the ionic liquid (IL) methyl trioctyl ammonium bistriflimide. Both the dispersion of the nanoparticles as well as the IL adsorption on ...
 RSC1 month ago

Ru(II)-dmso Complexes containing Azole-based Ligands: Synthesis, Linkage Isomerism and Catalytic Behaviour

Abstract Reaction of cis,fac-[RuCl2(dmso-S)3(dmso-O)], 1, with different azole (L) ligands leads to new [RuCl2(L)(dmso-S)3] compounds (L = CH3-pz-H, 2; NO2-pz-H, 3; CF3-pz-H, 4 and Br-Hind, 5). Complexes 2-5 have been characterized by analytical, ...
 RSC1 month ago

Hydrogen Evolution from Water under Aerobic Conditions Catalyzed by a Cobalt ATCUN Metallopeptide

Hydrogen is touted as an energy-dense carbon-free fuel; however, most hydrogen is currently produced via steam reforming of hydrocarbons. (1) A potentially more sustainable route to producing hydrogen is the reduction of aqueous protons. Hydrogenase ...
 Inorganic Chemistry1 month ago

Preparation of Pincer 4-Functionalized 2-Aminomethylbenzo[h]quinoline Ruthenium Catalysts for Ketone Reduction

Reaction of 1-naphthylamine with ethyl benzoylacetate gives the corresponding benzoyl acetamide derivative 1 , which undergoes cyclization to 4-phenylbenzo[ h ]quinolin-2(1 H )-one ( 2 ) in the presence of H 2 SO 4 . Bromination with POBr 3 , ...
 Organometallics1 month ago
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