The reaction of RuCl3·3H2O with 1,3,5-C5(tBu)3H3 afforded a dimeric Ru(III) dichloride complex, [Cp‡RuCl(μ-Cl)]2 (1b; Cp‡ = η5-1,2,4-C5(tBu)3H2). The treatment of 1b with gaseous oxygen afforded the tetravalent ruthenium μ-oxo complex ... Organometallics, 1 day ago
1 images for "rucl"
DNA/Protein Binding, Molecular Docking, and in Vitro Anticancer Activity of Some Thioether-Dipyrrinato Complexes
Syntheses and characterizations of the arene ruthenium [(η6-C6H6)RuCl(4-mtdpm)] (1), [(η6-p-MeC6H4Pri)RuCl(4-mtdpm)] (2), and structurally analogous rhodium/iridium complexes [(η5-C5Me5)RhCl(4-mtdpm)] (3) and [(η5-C5Me5)IrCl(4-mtdpm)] (4) ...Inorganic Chemistry, 2 weeks ago
Reactions of [RuCl2(PPh3)3] with Nitron and with the Enders Carbene: Access to Ruthenium(III) NHC Complexes
The reactions of [RuCl2(PPh3)3] with the Enders carbene 1,3,4-triphenyl-1,2,4-triazol-5-ylidene (1) and the instant carbene Nitron (2) respectively afforded the RuII chelates [RuCl(3)(PPh3)2] (3 = 3,4-diphenyl-1-o-phenylene-1,2,4-triazol-5-ylidene) ...Organometallics, 2 days ago
Reactivity study of low-coordinate phosphaalkene IMes=PPh with Grubbs first-generation ruthenium benzylidene complexes
New J. Chem. , 2013, Accepted Manuscript DOI : 10.1039/C3NJ01416A, Letter Timothy G Larocque, Gino G. Lavoie Reaction of IMes=PPh with RuCl 2 L 2 (CHPh) (L = PPh 3 and PCy 3 ) gave complexes with selectivity that is dependent on the metal ...RSC, 3 days ago
Enhanced Delivery of the RAPTA-C Macromolecular Chemotherapeutic by Conjugation to Degradable Polymeric Micelles
Macromolecular ruthenium complexes are a promising avenue to better and more selective chemotherapeutics. We have previously shown that RAPTA-C [RuCl2(p-cymene)(PTA)], with the water-soluble 1,3,5-phosphaadamantane (PTA) ligand, could be attached to ...Biomacromolecules, 2 weeks ago
While attempts to incorporate secondary phosphine ligands into the first-generation Grubbs catalyst RuCl2(PR3)2(═CHPh) (GI, R = Cy) were frustrated by decomposition (for HPCy2) or bulk (for HPtBu2), the mixed-phosphine complex ...Organometallics, 3 weeks ago
Tandem Cyclization of Enynes Containing a Thioether or Ether Linkage via Ruthenium Allenylidene and Vinylidene Complexes
The two aromatic S-enynes HC≡CCH(OH)(C6H4)SCH2C(R)═CH2 (1a, R = Me; 1b, R = H) containing olefinic groups with and without an internal methyl substitutent and the O-enyne HC≡CCH(OH)CMe2CH2OCH2C(Me)═CH2 (1c) also with an internal methyl ...Organometallics, 1 month ago
Chem. Commun. , 2013, Advance Article DOI : 10.1039/C3CC46596A, Communication Amrendra K. Singh, Benjamin G. Levine, Richard J. Staples, Aaron L. Odom Treatment of cis -RuCl 2 (PMe 3 ) 4 with LiNHAr provides d 6 -imido Ru(NAr)(PMe 3 ) 3 , which ...RSC, 1 month ago
on your WebpageAdd Widget >Get your members hooked!