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About 7 results for "rucl"

Mechanism Elucidation of the cistrans Isomerization of an Azol...

Synthesis and X-ray diffraction structures of cis and trans isomers of ruthenium and osmium metal complexes of general formulas (nBu4N)[cis-MCl4(NO)(Hind)], where M = Ru (1) and Os (3), and (nBu4N)[trans-MCl4(NO)(Hind)], where M = Ru (2) and Os (4) ... Inorganic Chemistry, 4 days ago

Ruthenium Complexes with Chiral Bis-Pinene Ligands: an Array of Subtle Structural Diversity

A new chiral derivative of the N,N-bis(2-pyridylmethyl)ethylamine (bpea) ligand, Me-pinene[5,6]bpea [(−)-L1], has been prepared from a new aldehyde building block [Me-pinene-aldehyde, (−)-4] arising from the monoterpene chiral pool. The ...

Inorganic Chemistry, 3 weeks ago

Characterization of an IronRuthenium Interaction in a Ferrocene Diamide Complex

Reaction of [fc(NH2)2]RuCl2(PPh3)2 (fc = 1,1′-ferrocenylene) with 2 equiv of KOtBu led to the formation of a diamido ruthenium complex, [fc(NH)2]Ru(PPh3)2, whose solid-state molecular structure revealed a short FeRu distance. A metal-to-metal ...

Inorganic Chemistry, 4 weeks ago

Nobel laureates and their research teams at American Chemical Society meeting

Contact: Michael Bernstein m_bernstein@acs.org 504-670-4707 (New Orleans Press Center, April 5-10) 202-872-6042 Michael Woods m_woods@acs.org 504-670-4707 (New Orleans Press Center, April 5-10) 202-872-6293 American Chemical Society NEW ORLEANS, ...

EurekAlert!, 1 month ago

[RuCl2(η6-p-cymene)(P*)] and [RuCl2(κ-P*-η6-arene)] Complexes Containing P-Stereogenic Phosphines. Activity in Transfer Hydrogenation and Interactions with DNA

The preparation of a series of half-sandwich ruthenium complexes, [RuCl2(η6-p-cymene)(P*)] (P* = S-PMeRR′) and [RuCl2(κ-P*-η6-arene)], containing P-stereogenic phosphines is reported. The borane-protected P-stereogenic phosphines have been ...

Organometallics, 1 month ago

Half sandwich complexes of chalcogenated pyridine based bi-(N, S/Se) and terdentate (N, S/Se, N) ligands with ([small eta]6-benzene)ruthenium(II): Synthesis, structure and catalysis of transfer hydrogenation of ketones and oxidation of alcohols

The half sandwich complexes [(η6C6H6)Ru(L)Cl][PF6] (1−5) have been synthesized by the reactions of (2arylchalcogenomethyl)pyridine [L=L1−L3] and bis(2pyridylmethyl)chalcogenide [L = L4−L5] (chalcogen = S, Se; Ar = Ph/ 2pyridyl for S, Ph for ...

RSC, 1 month ago