The reaction of trans-RuCl(C≡CC6H4R1-4)(dppe)2 (2: R1 = Me (a), C5H11 (b), OMe (c), CO2Me (d), NO2 (e), C≡CSiMe3 (f), C≡CBut (g), NH2 (h)), prepared in situ from reactions of [RuCl(dppe)2]OTf (OTf) with terminal alkynes in CH2Cl2 solutions ... Organometallics, 3 weeks ago
Magnetite nanoparticles coated with ruthenium via SePh layer as a magnetically retrievable catalyst for the selective synthesis of primary amides in an aqueous medium
The nanostructured magnetic oxide Fe3O4 has been coated with silica and then reacted with phenylselenyl chloride under a N2 atmosphere and RuCl3·xH2O successively in an aqueous medium to prepare Fe3O4@SiO2@SePh@Ru(OH)x nanoparticles (NPs) for the ...RSC, 3 weeks ago
The coupling reaction of N-propargyl semi-salen compound 1d on [Ru]-Cl ([Ru] = Cp(PPh3)2Ru) generates the carbene complex 3d containing a substituted 2H-chromene unit in 7 d. The precursor vinylidene complex 2d is isolated from the reaction of the ...Organometallics, 1 month ago
Reports from Jiangsu University Add New Data to Findings in Nanoparticles (Controlling Allotropism in Ruthenium Nanoparticles: A Pulsed-Flow...
Reports from Jiangsu University Add New Data to Findings in Nanoparticles (Controlling Allotropism in Ruthenium Nanoparticles: A Pulsed-Flow Supercritical Synthesis and in Situ Synchrotron X-ray Diffraction Study) By a News Reporter-Staff News ...HispanicBusiness.com, 1 month ago
By a News Reporter-Staff News Editor at Life Science Weekly -- Current study results on Hydrazines have been published. According to news originating from Coimbatore, India , by NewsRx correspondents, research stated, "A new set of ruthenium(II) ...HispanicBusiness.com, 1 month ago
Catalytic Activity and Fluxional Behavior of Complexes Based on RuHCl(CO)(PPh3)3 and Xantphos-Type Ligands
With RuHCl(CO)(PPh3)3 as the starting material, the complexes RuHCl(CO)(PPh3)(L) were prepared for L = Xantphos and closely related ligands. Their catalytic activity in the direct amination of cyclohexanol showed large differences depending on the ...Organometallics, 2 months ago
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