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About 9 results for "rucl"

Ruthenium-Catalyzed Direct CH Amidation of Arenes: A Mechanist...

State Key Laboratory of Applied Organic Chemistry, lanzhou University , Lanzhou, People's Republic of China Organometallics , Article ASAP DOI: 10.1021/om500080z Publication Date (Web): April 15, 2014 Copyright 2014 American Chemical Society ... Organometallics, 1 week ago

Dihydroperimidine-Derived PNP Pincer Complexes as Intermediates en Route to N-Heterocyclic Carbene Pincer Complexes

The reaction of N,N′-bis(dicyclohexylphosphinomethyl)dihydroperimidine (H2C(NCH2PCy2)2C10H6-1,8, 1a) with [RuCl2(PPh3)3] in THF affords the perimidinylidene-based N-heterocyclic carbene (per-NHC) pincer complex [RuCl2(OC4H8){═C(NCH2PCy2)2C10H6}] ...
 Organometallics1 week ago

Analysis of the Aromaticity of Five-Membered Heterometallacycles Containing Os, Ru, Rh, and Ir

We study the molecular structure and aromaticity in a series of experimental and new in silico designed five-membered heterometallacycles with general formula M(XC3H3)(PH3)2, where M = OsH3, OsCl3, OsCl2, RuCl2, RhCl2 or IrCl2 and X = NH, O, S, CH, ...
 Organometallics3 weeks ago

Ruthenium(II)-Catalyzed C(sp3)H α-Alkylation of Pyrrolidines

A catalytic system comprising [RuCl2(PPh3)3], AgOTf, and BINAP enabled atom- and step-economical additions of C(sp3)H bonds onto unactivated alkenes 2 under comparably mild reaction conditions. The pyridyl directing group was easily removed to ...
 Organic Letters1 month ago

Mechanistic Study on the Ruthenium-Catalyzed Direct Amination of Alcohols

The Ru-catalyzed direct amination of alcohols with ammonia was investigated for the RuHCl(CO)(PPh3)3/Xantphos system in order to gain mechanistic insight. For several Ru(II) precursor complexes the influence of different additives on catalytic ...
 Organometallics1 month ago

New Chemical Engineering Study Findings Have Been Reported by Researchers at South Central University for Nationalities

By a News Reporter-Staff News Editor at Journal of Engineering -- Data detailed on Chemical Engineering have been presented. According to news reporting originating in Wuhan , People's Republic of China , by VerticalNews journalists, research ...
 HispanicBusiness.com1 month ago

Combined Experimental and Computational Investigations of Rhodium- and Ruthenium-Catalyzed CH Functionalization of Pyrazoles with Alkynes

Detailed experimental and computational studies are reported on the mechanism of the coupling of alkynes with 3-arylpyrazoles at [Rh(MeCN)3Cp*][PF6]2 and [RuCl2(p-cymene)]2 catalysts. Density functional theory (DFT) calculations indicate a mechanism ...
 Journal of Organic Chemistry1 month ago

Ruthenium-Nitrosyl Complexes with Glycine, l-Alanine, l-Valine, l-Proline, d-Proline, l-Serine, l-Threonine, and l-Tyrosine: Synthesis, X-ray Diffraction Structures, Spectroscopic and Electrochemical Properties, and Antiproliferative Activity

The reactions of [Ru(NO)Cl5]2 with glycine (Gly), l-alanine (l-Ala), l-valine (l-Val), l-proline (l-Pro), d-proline (d-Pro), l-serine (l-Ser), l-threonine (l-Thr), and l-tyrosine (l-Tyr) in n-butanol or n-propanol afforded eight new complexes (18) ...
 Inorganic Chemistry2 months ago

Multiple CH Bond Cleavage of the Alkyl Group in (2,6-Dialkylphenoxo)ruthenium(II) Complexes

Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology , 2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan Organometallics , Article ASAP DOI: 10.1021/om5000248 Publication Date (Web): ...
 Organometallics2 months ago
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